Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 82, Issue 10, Pages 5424-5432Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.7b00367
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Funding
- National Natural Science Foundation of China [21372074]
- University of Birmingham
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A highly efficient chiral amidine derivative-catalyzed tandem Michael addition/lactonization of carboxylic acids and o-quinone methides (o-QMs) has been developed that enables the asymmetric synthesis of cis-3,4-dihydrocoumarins bearing contiguous tertiary stereogenic centers in high yields with excellent stereoselectivities.
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