Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 82, Issue 22, Pages 11909-11914Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.7b01652
Keywords
-
Categories
Funding
- Swedish Research Council [2015-04404]
- Swedish Research Council [2015-04404] Funding Source: Swedish Research Council
Ask authors/readers for more resources
The first synthesis of unsymmetric diaryliodonium salts directly from iodine and arenes is presented. The methodology provides diaryliodonium salts with the trimethoxyphenyl (TMP) moiety as dummy group. The protocol avoids the customary use of iodoarenes, which can be both expensive and toxic. Excess reagents are not required, and the reactions are performed under mild conditions. O-Arylations with these TMP salts were demonstrated to be highly chemoselective.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available