Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 82, Issue 3, Pages 1657-1665Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.6b02818
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Funding
- JSPS KAKENHI [25810019, 16K05679, 26410052]
- Faculty of Science, Shinshu University
- Grants-in-Aid for Scientific Research [16K05679, 17K05780, 26410052] Funding Source: KAKEN
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Tetrathiafulvalene (TTF) derivatives with 2-azulenyl substituents 5-11 were prepared by the palladium catalyzed direct arylation reaction of 2-chloroazulenes with TTF in good yield. Photophysical properties of these compounds were investigated by UV-vis spectroscopy and theoretical calculations. Redox behavior of the novel azulenesubstituted TTFs was examined by using cyclic voltammetry and differential pulse voltammetry, which revealed their multistep electrochemical oxidation and/or reduction properties. Moreover, these TTF derivatives showed significant spectral change in the visible region under the redox conditions.
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