Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 83, Issue 1, Pages 49-56Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.7b01905
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Funding
- National Nature Science Foundation of China [NSFC 21472213, 21272069]
- National Key Program [2016YFA0200302]
- Fundamental Research Funds for the Central Universities
- Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences
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Using the synthetic strategy of palladium catalyzed dual activation of both C-I and vicinal C-H bonds of diaryliodonium salts, we report an approach for direct diarylations of 2-bromobiphenyls or bromobenzenes. As a result, a wide range of triphenylenes with various substituents have been synthesized in good yields. These triphenylenes are expected to be employed in the bottom -up synthesis of functional aromatic molecules in material science.
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