Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 82, Issue 17, Pages 8950-8957Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.7b01375
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Funding
- National Natural Science Foundation of China [21562024, 21562025]
- Science Fund for Distinguished Young Scholars of Jiangxi Province [20162BCB23023]
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o-Aminophenol (OAP) has been discovered as practical precursor of directing group (DG) in the palladium-catalyzed aromatic C-H arylation of benzamides. This newly identified, simple, and low cost DG has exhibited broad substrate tolerance in the rapid synthesis of various o-arylated benzamides via direct assemblies of benzoyl chlorides, aryl iodides, and different o-aminophenols in the form of step economical multicomponent reaction.
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