Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 82, Issue 15, Pages 8282-8289Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.7b01313
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Funding
- Henan Province Key Laboratory of New Optoelectronic Functional Materials
- Science and Technology Foundation of Henan Province
- National NSF of China [21372041]
- Jilin Province Key Laboratory of Organic Functional Molecular Design and Synthesis [130028651]
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The copper-catalyzed highly regioselective aminodifluoroalkylation of alkynes and alpha-bromodifluoroacetamides was realized for the first time. With this method, 3,3difluoro-1H-pyrrol-2(3H)-ones were constructed in a single step from various alkynes and a-bromodifluoroacetamides substrates without using any extra oxidant.
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