Journal
CATALYSIS SCIENCE & TECHNOLOGY
Volume 9, Issue 20, Pages 5698-5711Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cy01553a
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Funding
- Chiang Mai University
- Center of Excellence for Innovation in Chemistry (PERCH-CIC)
- Ministry of Higher Education, Science, Research and Innovation
- Center of Excellence (CoE) in Materials Science and Technology
- Science Achievement Scholarship of Thailand
- Graduate School, Chiang Mai University, Thailand
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A rapid microwave synthesis route for the fabrication of ZnIn2S4 powder and ZnIn2S4/WS2 composites is presented. Firstly, the effects of different sulfur sources - thioacetamide and l-cysteine - on the physicochemical properties and photocatalytic H-2 production of the synthesized ZnIn2S4 were investigated. It was found that well-defined flower-like ZnIn2S4 microspheres obtained from l-cysteine facilitated a relatively higher H-2 production rate. Then, different loadings of WS2 were introduced into the well-defined flower-like ZnIn2S4 microspheres aiming to improve its photocatalytic H-2 production. Compared to pure ZnIn2S4 and WS2, all ZnIn2S4/WS2 composite photocatalysts exhibited enhanced photocatalytic H-2 production in the presence of Na2S/Na2SO3 as sacrificial reagents under UV-visible irradiation, where the ZnIn2S4/WS2-40% wt composite had the highest photocatalytic activity. For this material, 293.3 and 76.6 mu mol h(-1) g(-1) of H-2 gas were produced under UV-visible and visible light irradiation, respectively. In addition, the photoreduction activity of hexavalent chromium (Cr(vi)) by ZnIn2S4/WS2-40% wt was also investigated under visible light irradiation and it was observed that 98.5% of Cr(vi) was reduced within 90 min at pH 4.
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