Journal
CHEMICAL COMMUNICATIONS
Volume 55, Issue 86, Pages 13008-13011Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cc06544j
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Funding
- National Natural Science Foundation of China [21476041, U1608224, 61633006]
- State Key Laboratory of Fine Chemicals
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A visible light-mediated alpha-functionalization of 1,3-dicarbonyl compounds with switchable selectivity induced by disulfide is disclosed. Upon irradiation with visible light, the metal- and base-free alpha-hydroxylation or alpha-hydroxymethylation reaction proceeded smoothly through a disulfide-catalyzed oxidation under mild conditions. The combination of a continuous-flow strategy could further improve the reaction efficiencies.
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