Journal
CHEMICAL COMMUNICATIONS
Volume 55, Issue 86, Pages 12988-12991Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cc07175j
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Funding
- Lundbeck Foundation [R250-2017-1292]
- Technical University of Denmark
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Herein, we report stoichiometric investigations embodying the first highly enantioselective aryl-aryl coupling facilitated by a gold complex. With up to 91% ee, this is the first demonstration of a transmetalation and C(sp(2))-C(sp(2)) reductive elimination sequence with high enantioselectivity using a gold complex. The results offer a basis for development of enantioselective gold-catalyzed aryl-aryl coupling reactions.
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