Journal
CHINESE JOURNAL OF CATALYSIS
Volume 40, Issue 12, Pages 1841-1846Publisher
ELSEVIER
DOI: 10.1016/S1872-2067(19)63379-6
Keywords
Photoredox catalysis; Nickel catalysis; Construction of carbon-phosphorus bond; Heterogeneous
Funding
- National Science Foundation of China [21822103, 21820102003, 21772052, 21772053, 21572074, 21472057]
- Program of Introducing Talents of Discipline to Universities of China (111 Program) [B17019]
- Natural Science Foundation of Hubei Province [2017AHB047]
- International Joint Research Center for Intelligent Biosensing Technology and Health
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An efficient C-P bond formation reaction was developed by virtue of the synergetic catalysis strategy by merging heterogeneous photocatalysis and nickel catalysis. This platform utilizing cadmium sulfide semiconductors as heterogeneous photocatalysts and nickel complexes as transition metal catalysts provided a variety of organophosphorus compounds from readily available aryl and vinyl halides, as well as aryl triflates, with generally a good-to-excellent reaction efficiency (31 examples, 46%-98% yields). The current protocol features mild reaction conditions, a broad substrate scope, recyclability of photocatalysts, and inexpensive catalysts, thus defining the practical and economic proprieties of the present catalyst system. (C) 2019, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.
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