Journal
GREEN ENERGY & ENVIRONMENT
Volume 4, Issue 2, Pages 116-120Publisher
KEAI PUBLISHING LTD
DOI: 10.1016/j.gee.2019.03.001
Keywords
Ionic liquid; Photosensitizer; Redox active; Visible light; Vitamin B-12
Categories
Funding
- JSPS KAKENHI [18H04265, JP16H04119]
- JSPS
- PAN [AJ180081 (30-0004-04)]
- Nippon Sheet Glass Foundation [HAKF541800]
- Grants-in-Aid for Scientific Research [18H04265] Funding Source: KAKEN
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The redox active ionic liquid, 1-ethyl-4-(methoxycarbonyl)pyridinium bis(trifluoromethanesulfonyl)amide (RIL), was synthesized from its iodide form by an anion exchange reaction of Li(NTf2) with viscos liquid (eta = 122 cP at 25 degrees C) and characterized by NMR, IR, and elemental analysis. The compound showed reversible redox couples at -0.65 V and -1.48 V vs. Ag/AgCl and worked as an electron mediator in the B-12 complex/[Ru(bpy)(3)]Cl-2 photosensitizer catalytic system under visible light irradiation. The catalytic efficiency in the RIL was higher than those in DMF, MeOH, and the redox inactive ionic liquid, 1-butyl-3-methyl imidazolium bis(trifluoromethylsulfonyl)amide. (C) 2019, Institute of Process Engineering, Chinese Academy of Sciences. Publishing services by Elsevier B.V.
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