4.5 Article

Enhanced Low-temperature NH3-SCR Activity over Ce-Ti Oxide Catalysts by Hydrochloric Acid Treatment

Journal

AEROSOL AND AIR QUALITY RESEARCH
Volume 19, Issue 11, Pages 2381-2386

Publisher

TAIWAN ASSOC AEROSOL RES-TAAR
DOI: 10.4209/aaqr.2019.04.0184

Keywords

NH3-SCR; Ce-Ti oxide; Hydrochloric acid treatment; Activity

Funding

  1. National Natural Science Foundation of China [51506226]
  2. Natural Science Foundation of Shandong Province [ZR2015EM010]
  3. Fundamental Research Funds for the Central Universities [19CX02031A]

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The effect of hydrochloric acid treatment on Ce-Ti oxides was investigated for selective catalytic reduction of NO with NH3. The results showed that hydrochloric acid treatment had a positive effect on the low-temperature activity of Ce-Ti oxides. The improved activity of Ce-Ti oxides could be attributed to the increase in the concentration of Ce as well as the amount of Ce3+ and chemisorbed oxygen on the catalyst surface. In addition, the enhanced Lewis acidity could improve NH3 absorption, and was also a key factor to enhance the low-temperature activity of Ce-Ti oxides.

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