Journal
JOURNAL OF MATERIALS CHEMISTRY A
Volume 7, Issue 42, Pages 24374-24388Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9ta09902f
Keywords
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Funding
- National Natural Science Foundation of China [21571040]
- Young Top-Notch Talent of National Ten Thousand Talent Program
- Natural Science Foundation of Heilongjiang Province [QC2017046]
- Fundamental Research Funds for the Central Universities
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Designing and exploring earth-abundant but high-performance electrode materials are of crucial significance for the future large-scale development of supercapacitors. Herein, a facile anionic P-substitution strategy is used to in situ decorate ternary Ni-S-P nanoparticles on graphene nanosheets (G/Ni-S-P) for supercapacitors for the first time. Benefitting from the unique hierarchical structure and positive synergistic effects between each component, the resultant G/Ni-S-P composite delivers a spectacular specific capacity of 1406 C g(-1) at 1 A g(-1) with an outstanding rate capability of 60.2% at 120 A g(-1), which is highly superior to those of the previously reported nickel based composites. The asymmetric supercapacitor assembled with the G/Ni-S-P and graphene/FeOOH composite as the cathode and anode exhibits high energy density up to 58.1 W h kg(-1) and superb electrochemical stability with 4.9% decay after 30 000 continuous charge/discharge cycles. These intriguing electrochemical performances indicate that the G/Ni-S-P composite has enormous potential application in high-performance energy storage systems in the future.
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