Journal
DALTON TRANSACTIONS
Volume 48, Issue 41, Pages 15657-15667Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9dt02419k
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- SERB [CRG/2018/000430]
- Australian Research Council
- UGC (India)
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The structural, magnetic and theoretical aspects are described for three triangular lanthanide complexes, [TbIII3(OH)(teaH(2))(3)(paa)(3)]Cl-2 (1), [DyIII3(OH)(teaH(2))(3)(paa)(3)]Cl-2 (2) and [HoIII3(OH)(teaH(2))(3)(paa)(3)]Cl-2 (3), and a hexanuclear wheel of formula [DyIII6(pdeaH)(6)(NO3)(6)] (4) [teaH(3) = triethanolamine, paaH = N-(2-pyridyl)-acetoacetamide and pdeaH(3) = 3-[bis(2-hydroxyethyl)amino]propan-1-ol]. Each complex displays single molecule toroidal behaviour as rationalised using high-level ab initio calculations. Complexes 2 and 3 are the first examples of mixed moment single molecule toroidal complexes featuring non-Kramers ions.
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