Journal
CHEMICAL COMMUNICATIONS
Volume 55, Issue 80, Pages 12020-12023Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cc06707h
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Funding
- Australian Research Council [DE170100200]
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A crystalline 3D hydrogen bonded framework is assembled in water from tetrahedral tetraamidinium cations and antielectrostatically hydrogen bonded bicarbonate dimers. The framework forms in water, and represents a clear demonstration of the potency of these anti-Coulombic hydrogen bonds. Gentle heating of the framework (50 degrees C) releases CO2 and water to give the neutral tetraamidine compound.
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