4.6 Article

Direct Production of Silicon Nanostructures with Electrochemical Nanoimprinting

Journal

ACS APPLIED ELECTRONIC MATERIALS
Volume 1, Issue 7, Pages 1070-1075

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acsaelm.9b00281

Keywords

electrochemical nanoimprinting; metal-assisted chemical-etching; silicon nanostructures; master stamp

Funding

  1. National Key Research and Development Program of China [2017YFA0206002]
  2. National Natural Science Foundation of China [61804169, U1832217, 61875225, 61821091, 61774166]

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We demonstrate an electrochemical nanoimprinting process-termed as Mac-Imprint-to produce different silicon nanostructures. A master stamp featuring high-aspect-ratio nanostructures with Ta film as the blocking layer and Au nanostructures as the catalyst is realized by electron-beam lithography followed by Au electroplating. In particular, we investigate the generated monocrystalline silicon nanostructure characteristics and realize a 20 nm minimum feature size. Moreover, we demonstrate the creation of structural color image of a rooster with an average pixel size of 300 nm (similar to 42 000 dpi). Our results suggest that such a simple process has prospective applications ranging from optoelectronics to luminescent devices.

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