Journal
ACS APPLIED ELECTRONIC MATERIALS
Volume 1, Issue 8, Pages 1433-1438Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acsaelm.9b00248
Keywords
inorganic chemistry; materials science; physical properties; semiconductors; synthesis; UV-vis spectroscopy; X-ray crystallography; nitride; thin film growth; molecular beam epitaxy
Funding
- JST CREST, Japan [JPMJCR17J2]
- Ministry of Education, Culture, Sports, Science, and Technology (MEXT) through the Element Strategy Initiative to Form Core Research Center
- Japan Society for the Promotion of Science (JSPS) [17H01318, 18H01700]
- Support for Tokyotech Advanced Research (STAR)
- Grants-in-Aid for Scientific Research [18H01700] Funding Source: KAKEN
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Zinc-based nitride CaZn2N2 films grown by molecular beam epitaxy (MBE) with a plasma-assisted active nitrogen-radical source are promising candidates of next-generation semiconductors for light-emitting diodes and solar cells. This nitride compound has previously only been synthesized in a bulk form by ultrahigh-pressure synthesis at 5 GPa. Three key factors have been found to enable heteroepitaxial film growth: (i) precise tuning of the individual flux rates of Ca and Zn, (ii) the use of GaN template layers on sapphire c-plane as substrates, and (iii) the application of MBE with an active N-radical source. Because other attempts at physical vapor deposition and thermal annealing processes have not produced CaZn2N2 films of any phase, this rf-plasma-assisted MBE technique represents a promising way to stabilize CaZn2N2 epitaxial films. The estimated optical band gap is similar to 1.9 eV, which is consistent with the value obtained from bulk samples. By unintentional carrier doping, n- and p-type electronic conductions are attained with low carrier densities of the order of 10(13) cm(-3). These features represent clear advantages when compared with Zn-based oxide semiconductors, which usually have much higher carrier densities irrespective of their intentionally undoped state. The carrier mobilities at room temperature are 4.3 cm(2)/(V-s) for electrons and 0.3 cm(2)/(V-s) for hole carriers, which indicates that transport properties are limited by grain boundary scattering, mainly because of the low-temperature growth at 250 degrees C, which realizes a high nitrogen chemical potential.
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