Journal
ACS APPLIED ELECTRONIC MATERIALS
Volume 1, Issue 8, Pages 1378-1386Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acsaelm.9b00004
Keywords
OFETs; perylene bisimides; heteroatom annulation; n-type semiconductor; thin films; electron mobility
Funding
- Science and Engineering Board (SERB), DST, Govt. of India [CRG/2018/000362, SB/S1/PC-37/2012, 2012/34/31/BRNS/1039]
- BRNS-DAE [CRG/2018/000362, SB/S1/PC-37/2012, 2012/34/31/BRNS/1039]
- Department of Science and Technology (DST), India [DST/SERB/EMR/2014/000034]
- DST-Max Planck Society, Germany [IGSTC/MPG/PG(PKI)/2011A/48]
- Ministry of Human Resource Development for Centre of Excellence in FAST [S -7/2014-TS-VII]
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We report the synthesis of bay-annulated (N, S, and Se) perylene bisimides (PBIs) and their structural, thermal, photophysical, electrochemical, and morphological characterization. In addition, their application in organic field effect transistors (OFETs) is demonstrated. All the PBIs except PBI-Se exhibited bright emission in solutions and thin films. Planar molecular structure, variation of the HOMO-LUMO levels, and the energy gaps were evaluated with the help of Gaussian simulation. Morphology of all the synthesized PBIs has been investigated with the aid of polarizing optical microscopy and atomic force microscopy (AFM). AFM topographical images exhibited surface roughness value ranging from 1.98 to 3.52 nm. Powder X-ray diffraction data revealed the lamellar packing of these molecules in the thermally evaporated thin films. It has been witnessed that the OFET device with top-contact bottom-gate configuration, where the PBI-S served as the semiconducting layer, exhibited the highest electron mobility (mu = 4.40 X 10(-3) cm(2) V-1 s(-1)) in comparison to PBI-N and PBI-Se, due to the better thin film growth mechanism. These materials are promising from the viewpoint of n-type materials that can be utilized in organic electronics.
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