Hydrothermal tuning of the morphology and crystallite size of zeolite nanostructures for simultaneous adsorption and photocatalytic degradation of methylene blue dye

We herein have reported on tuning of the morphology and crystallite size of the hydrothermally prepared zeolite nanostructures by using different aluminum sources. The investigation revealed that aluminum sulfate and aluminum chloride precursors produced non-crystalline forms, while aluminum isopropoxide, alumina, and aluminum metal precursors generated analcime nanopartides with crystallite size of ca. 94.79, 112.57, and 105.87 nm, respectively. However, sodium aluminate precursor gave a mixture of analcime and nacrite phases with a crystallite size of ca. 77.95 nm. The as-prepared nanostructures were identified using XRD, FT-IR, FE-SEM, EDS, UV-Vis spectroscopy and BET surface area. The results exhibited that the direct optical energy gaps (E-g) and BET surface area were found to be (3.29 eV and 20.18 m(2)/g), (3.15 eV and 16.28 m(2)/g), (3.21 eV and 18.67 m(2)/g), and (2.69 eV and 17.82 m(2)/g) for the zeolite products prepared using aluminum isopropoxide, sodium aluminate, alumina, and aluminum metal precursors, respectively. The results also showed that the as-prepared zeolite nanostructures could be simultaneously used as adsorbents and photocatalysts for the removal of methylene blue (MB) dye from aqueous solutions. The adsorption of methylene blue dye over the zeolite adsorbents obeys pseudo-second-order model and intra-particle diffusion model. Interestingly, zeolite photocatalyst prepared using aluminum isopropoxide degraded the MB dye with percentage of 85% and 100% within 180 and 110 min in the presence of UV and (UV + H2O2), respectively. The degradation processes followed the pseudo-first-order model. The prepared zeolites are proposed as promising candidates for the removal of MB from aqueous media. (C) 2017 Elsevier B.V. All rights reserved.