4.7 Article

Temperature and solvent dependent thermodynamic behavior of tetrabromobisphenol A

Journal

JOURNAL OF MOLECULAR LIQUIDS
Volume 241, Issue -, Pages 150-162

Publisher

ELSEVIER SCIENCE BV
DOI: 10.1016/j.molliq.2017.05.118

Keywords

Tetrabromobisphenol A; Solubility; Thermodynamic property; Thermodynamic model

Funding

  1. National Natural Science Foundation of China [81361140344, 21376164]
  2. National 863 Program [2015AA021002]
  3. Major Project of Tianjin [15JCZDJC33200]
  4. Major National Scientific Instrument Development Project [21527812]

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The mole fraction solubility of tetrabromobisphenol A in nine pure solvents and two binary solvents was determined using the gravimetric method. Different thermodynamic models were employed to analyze the dissolution behavior of tetrabromobisphenol A in pure and binary solvents. In addition, the analysis of the thermodynamic properties implies that the lower mixing Gibbs free energy is, the stronger interaction between solute and solvent is, leading to higher solubility. (C) 2017 Elsevier B.V. All rights reserved.

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