Journal
CHEMICAL COMMUNICATIONS
Volume 55, Issue 91, Pages 13693-13696Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cc07637a
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Funding
- National Natural Science Foundation of China [21502155]
- Natural Science Foundation of Chongqing [cstc2018jcyjA1315]
- Fundamental Research Funds for the Central Universities [XDJK2019AA003]
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Disclosed herein is a Pd(ii)-catalyzed C(sp(3))-H/P-H oxidative cross-coupling reaction between 8-methylquinolines with H-phosphonates or diarylphosphine oxides via chelation-assisted C(sp(3))-H bond activation. The protocol exhibits a relatively broad functional-group tolerance and exclusive chemo- and regioselectivity. Furthermore, detailed mechanistic studies support the proposed reaction pathway.
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