Journal
CHEMICAL COMMUNICATIONS
Volume 55, Issue 89, Pages 13410-13413Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cc06637c
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Funding
- German Research Council (DFG, Emmy Noether Fellowship) [TE1101/2-1]
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Copper(i)/N-heterocyclic carbene complexes enable a transfer semihydrogenation of alkynes employing simple and readily available alcohols such as isopropanol. The practical overall protocol circumvents the use of commonly employed high pressure equipment when using dihydrogen (H-2) on the one hand, and avoids the generation of stoichiometric silicon-based waste on the other hand, when hydrosilanes are used as terminal reductants.
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