4.7 Article

An unprecedented 2D covalent organic framework with an htb net topology

Journal

CHEMICAL COMMUNICATIONS
Volume 55, Issue 89, Pages 13454-13457

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cc06780a

Keywords

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Funding

  1. National Natural Science Foundation of P. R. China [21603076, 21571070]
  2. Natural Science Foundation of Guangdong Province [2016A030310437, 2018A030313193]
  3. Office of Science, Office of Basic Energy Sciences, of the U.S. Department of Energy [DE-AC02-05CH11231]

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A 2D imine-linked COF with a hitherto unreported htb type topology was synthesized from a linear diamine linker and a judiciously designed tetra-aldehyde building block. This work opens the door to the development of COFs with unprecedented topologies and may broaden the scope of COF functional materials by pore size and pore surface engineering.

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