Journal
JOURNAL OF MOLECULAR LIQUIDS
Volume 225, Issue -, Pages 251-259Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.molliq.2016.11.040
Keywords
Azobenzene; Azotolane; Liquid crystal; Monomer
Funding
- CONACYT - Mexico [130902, 242232, 276107]
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Four functional methacrylate monomers, two of them carrying a biphenyleneazobenzene group, and the other two an azotolane group, were synthesized. The synthetic route involved several reactions, among which are the Suzuki-Miyaura and Sonogashira cross-coupling reactions that allowed us to prepare long rigid rodlike azobenzene cores. The chemical structure of these new azo-monomers was confirmed by proton nuclear magnetic resonance CH NMR) spectroscopy, and the thermotropic liquid-crystalline behavior was determined from differential scanning calorimetry (DSC), polarizing optical microscopy (POM) and X-ray diffraction (XRD) analyses. The four monomers showed a mesomorphic behavior that extends over a broad temperature range. The phase transitions of the monomers carrying a biphenyleneazobenzene core were much broader and weaker than those of monomers carrying an azotolane group. Also, the former showed no crystallization in cooling to room temperature. The four studied monomers displayed liquid crystal phases with lamellar order (SmA and SmC), but only those carrying an azotolane core developed an additional nematic phase. The lamellar stacking of monomers is discussed in terms of lateral interactions between the rigid rodlike cores. Both types of monomers showed a trans to cis photo-conversion of around 90% when irradiated with UV-light. These new monomers are precursors of photo-responsive liquid crystal polymers. (C) 2016 Elsevier B.V. All rights reserved.
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