Journal
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
Volume 426, Issue -, Pages 368-375Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.molcata.2016.10.019
Keywords
Pincer-Iridium complexes; Alkane dehydrogenation; Dienes; C-H bond activation; Catalytic alkane conversion
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Funding
- NSF under the CCI Center for Enabling New Technologies through Catalysis (CENTC) Phase II Renewal [CHE-1205189]
- Chevron Energy Technology Company
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [1205189] Funding Source: National Science Foundation
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Conjugated dienes are desirable reagents for several important applications. We report that sterically uncrowded PCP-pincer iridium complexes, including precursors of ((PCP)-P-iPr4)Ir and ((PCP)-P-Me2tBu2)Ir, catalyze the transfer dehydrogenation of pentane, using high concentrations of t-butylethylene (TBE) as hydrogen acceptor, to give high yields of 1,3-pentadiene (piperylene). Piperylene yields are ca. 100-fold greater than those obtained with the more widely used di(t-butyl)phosphino substituted pincer iridium catalysts. This represents, to our knowledge, the first reported high-yield synthesis of dienes via the dehydrogenation of n-alkane using molecular catalysts. To our knowledge, this is the first reported high-yield synthesis of dienes achieved via the dehydrogenation of n-alkane using molecular catalysts. (C) 2016 Elsevier B.V. All rights reserved.
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