Journal
DALTON TRANSACTIONS
Volume 48, Issue 45, Pages 16869-16872Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9dt04230j
Keywords
-
Categories
Funding
- Georgia Institute of Technology
- Department of Energy, Heavy Element Chemistry Program [DE-SC0019385]
- U.S. Department of Energy (DOE) [DE-SC0019385] Funding Source: U.S. Department of Energy (DOE)
Ask authors/readers for more resources
The direct synthesis of neutral, divalent samarium and europium complexes supported by the bulky bis(tris-tert-butoxysilyl)amide (BTTSA) ligand via oxidative transmetallation is reported. Through the use of a copper(i) ligand complex, conventional lanthanide halide starting materials for complex formation are circumvented and the clean formation of divalent complexes is achieved directly from the bulk metal. The structures of the [Ln(BTTSA)(2)] (Ln = Sm, Eu) complexes are isotypic, presenting divalent lanthanide ions with distorted, six-coordinate geometries.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available