Journal
CHEMICAL SCIENCE
Volume 10, Issue 45, Pages 10510-10515Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9sc04073k
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Funding
- 973 Programs [2015CB856600]
- National Natural Science Foundation of China [21425205]
- Changjiang Scholars and Innovative Research Team in University (PCSIRT)
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A novel class of cyclic phosphine derived bifunctional catalysts (Le-Phos) is reported, which can be readily prepared from inexpensive and commercially available starting materials and exhibit good performances in enantioselective gamma-addition reactions of N-centered nucleophiles and allenoates under mild conditions. The salient features of this reaction include high product yields, good enantioselectivity, mild reaction conditions, and broad substrate scope and gram-scale scalability.
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