4.7 Article

Core-shell hybrid nanowires with Co nanoparticles wrapped in N-doped porous carbon for lightweight microwave absorption

Journal

DALTON TRANSACTIONS
Volume 48, Issue 40, Pages 15263-15271

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c9dt03447a

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Funding

  1. National Nature Science Foundation of China [51971111]
  2. Open Research Fund of Jiangsu Provincial Key Laboratory for Nanotechnology of Nanjing University
  3. Jiangsu Provincial Key Laboratory of Bionic Functional Materials

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Exploration of lightweight and thin electromagnetic (EM) wave absorption materials is still urgent because of the issues related to EM pollution. In this work, one-dimensional core-shell nanowires with Co-nanoparticles embedded in N doped porous carbon (Co@NPC NWs) have been successfully fabricated for microwave absorption. The obtained Co@NPC composites with a pea-like structure have high loading of Co nanoparticles (68 wt%) encapsulated by the defective carbon shell. Thanks to these special characteristics, the Co@NPC NWs exhibit superb microwave absorption properties in comparison with the pristine nano-Co powder and NPC. The strong reflection loss (RL) of -48 dB could be achieved at a thickness of only 1.45 mm. In addition, the effective absorption bandwidth is up to 5.2 GHz. These superb absorption properties coupled with thin thickness endow the Co@NPC NWs with great potential for application in lightweight EM wave absorption.

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