Journal
SYNOPEN
Volume 3, Issue 4, Pages 142-147Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0039-1690337
Keywords
biomimetic synthesis; iodofunctionalization; selenium catalysis; iodination; aqueous reaction
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Funding
- Fundacao de Amparo a Pesquisa do Estado de Sao Paulo (Sao Paulo Research Foundation)
- FAPESP [2017/21990-0]
- National Council for Scientific and Technological Development (CNPq)
- Coordination for the Improvement of Higher Education Personnel (CAPES)
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A biomimetic iodofunctionalization of aromatic and heteroaromatic compounds has been developed using NaI as a source of iodine and 30% H (2) O (2) as a mild oxidant, as well as SeCl (4) as a commercially available catalyst in water without a co-solvent. The method affords iodinated compounds in isolated yields of 37 to 99%. The catalytic system has potential for the bromination of aromatic substrates.
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