Journal
CHEMICAL COMMUNICATIONS
Volume 55, Issue 95, Pages 14283-14286Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cc06828g
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In this paper we describe unprecedented Ir(iii) complexes of 5-(2-pyridyl)-1,2,4-triazine and their reactivity towards the strained cyclooctyne BCN. The coordination of a 1,2,4-triazine ring to an iridium(iii) ion drastically increases the speed of the reaction, showing the second order rate constant of 8 M-1 s(-1), the record value to date for a triazine-BCN reaction.
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