4.7 Article

A biomimetic self-assembled cobaloxime@CdS/rGO hybrid for boosting photocatalytic H2 production

Journal

CHEMICAL COMMUNICATIONS
Volume 55, Issue 96, Pages 14490-14493

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cc08512b

Keywords

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Funding

  1. National Natural Science Foundation of China [U1662114, 21871102, 21773151]
  2. Knowledge Innovation Program of Shenzhen Science and Technology Innovation Programof Shenzhen, China [JCYJ20170307154314576]
  3. Shantou University Initial Funding [NTF16010]
  4. Key Laboratory for Preparation and Application of Ordered Structural Materials of Guangdong Province in Shantou University

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A biomimetic CoPe@CdS/rGO hybrid that self-assembles via the integration of a molecular cobalt catalyst and CdS nano-semiconductor on reduced graphene oxide was constructed for boosting photocatalytic H-2 production. Photoinduced electron transfer from CdS/rGO to the molecular catalyst occurs and a long-lived charge-separation state forms for high H-2 production.

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