Journal
CHEMICAL COMMUNICATIONS
Volume 55, Issue 96, Pages 14434-14437Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cc07150d
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Funding
- Estonian MER [PUT692, PRG399, IUT 19-9]
- ERDF [CoE 3.2.0101.08-0017, CoE 2014-2020.4.01.15-0013, CoE TK134]
- H2020-FETOPEN [828779]
- South-Central University for Nationalities [YZZ16005]
- High-Performance Computing Center of the University of Tartu
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Chiral cyclohexanohemicucurbit[n]urils (n = 6, 8) (cycHCs) are able to bind guests through multiple outer surface interactions, which in the case of planar zinc porphyrins leads to induction of chirality. Crystal structures of complexes of complementary sized hosts revealed social self-sorting, while in the solution phase one cycHC can accommodate up to three porphyrin molecules with log K-total 9.
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