Journal
DALTON TRANSACTIONS
Volume 48, Issue 46, Pages 17179-17183Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9dt04071d
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Funding
- Universidad del Pais Vasco (UPV/EHU) [GIU13/06]
- MINECO [CTQ2015-65268-C2]
- Gobierno Vasco [IT1180-19]
- IKERBASQUE
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The first phosphine-stabilized cationic rhodium silylene complex is reported. A dihydrido-silylene-Rh(iii) compound reacts with water and alcohols forming alkoxysilyl-Rh(iii) complexes and hydrogen gas. Moreover, benzophenone reacts with a cationic silylene rhodium complex leading to the reduction of the carbonyl group and the formation of an alkoxysilyl-Rh(iii) compound which has been identified as a likely intermediate in the mechanism for the hydrosilylation of ketones proposed by Hofmann and Gade.
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