Journal
CHINESE JOURNAL OF ORGANIC CHEMISTRY
Volume 39, Issue 11, Pages 2989-3012Publisher
SCIENCE PRESS
DOI: 10.6023/cjoc201904037
Keywords
copper-catalysis; heterocyclic compounds; N-O cleavage; cascade reaction; rearrangement reaction
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Funding
- Overseas 100 Talents Program of Guangxi Higher Education
- One Thousand Young and Middle-Aged College and University Backbone Teachers Cultivation Program of Guangxi Zhuang Autonomous Region
- Natural Science Foundation of Guangxi Zhuang Autonomous Region [2016GXNSFFA380005]
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N-O bond cleavage is one of the most efficient and powerful strategies to introduce N- or O-functional groups into molecules in organic synthesis. Copper catalyst, as the abundant in earth and inexpensive advantages has been widely used to construct C-N and C-O bond. Furthermore, N-O bond cleavage has been successfully applied in the total synthesis of natural products and pharmaceuticals. The new development of copper-catalyzed N-O bond cleavage and its application in the total synthesis of natural products and pharmaceuticals in recent years have been summarized.
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