Journal
CHEMICAL SCIENCE
Volume 10, Issue 47, Pages 10944-10947Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9sc04199k
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Funding
- Indiana University
- NIH [R01GM114443, R35GM128779]
- Vice Provost for Research through the Research Equipment Fund
- NSF [CHE1726633]
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Nickel-catalyzed 1,2-carboboration of alkenes is emerging as a useful method for chemical synthesis. Prior studies have been limited to only the incorporation of aryl groups. In this manuscript, a method for the 1,2-benzylboration of unactivated alkenes is presented. The reaction combines readily available alkenes, diboron reagents and benzylchlorides to generate synthetically versatile products with control of stereochemistry. The utility of the products as well as the mechanistic details of the process are also presented.
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