Journal
CRYSTENGCOMM
Volume 21, Issue 44, Pages 6688-6692Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9ce01416k
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Funding
- National Natural Science Foundation of China [21572032, 21971041]
- Natural Science Foundation of Fujian Province [2018J01431]
- Research Foundation of Education Bureau of Fujian Province [JT180813]
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The combination of hexacyanoferrate anions with protonated N,N'-dipyridyl-naphthalene diimide tectons resulted in a novel cuboid 3-D H-bonded anion-coordinated framework. Induced by anion-pi interactions, such a unique framework is further catenated into an unprecedented five-fold interpenetrated D-A hybrid heterostructure with 1-D hexacyanoferrate polyanions and naphthalene diimide aggregates as electron donors and acceptors, respectively. The photophysical and photochemical properties have also been discussed.
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