4.7 Article

A non-luminescent Eu-MOF-based turn-on sensor towards an anthrax biomarker through single-crystal to single-crystal phase transition

Journal

CHEMICAL COMMUNICATIONS
Volume 55, Issue 99, Pages 14918-14921

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cc08206a

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Funding

  1. Foundation of the Natural Science Foundation of China [21771077, 21771084, 21621001]
  2. National Key Research and Development Program of China [2016YFB0701100]
  3. 111 project [B17020]
  4. Program for JLU Science and Technology Innovative Research Team (JLUSTIRT)

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A porous NH2-MOF-76(Eu) (MOF 1) with unexpected non-luminescence was designed and synthesized. It exhibits selective fluorescence recovery for sensing dipicolinic acid (DPA), a biomarker of Bacillus anthracis. Moreover, a new europium-based MOF (MOF 2) with evident channel changes was obtained through a single-crystal to single-crystal phase transition.

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