Journal
CHEMICAL COMMUNICATIONS
Volume 55, Issue 99, Pages 14972-14975Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cc08595e
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Funding
- Ministerio de Ciencia y Universidades [PGC2018-093382-B-I00]
- Universitat Jaume I [UJI-B2017-07]
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A nanometer-sized tetrapalladium metallosquare with a pyrene-bisimidazolylidene ligand was found to display a perfect-sized cavity for the encapsulation of three heteroguests, enabling the formation of quintuple D-A-D-A-D stacks. The encapsulating properties of the metallosquare are clearly determined by the presence of the pyrene panels, which endow the metallosquare with a three-dimensional shape, and also behave as effective antennae for pi-stacking interactions.
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