Journal
CHEMICAL COMMUNICATIONS
Volume 55, Issue 99, Pages 14954-14957Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cc08703f
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Funding
- University of Virginia
- Mississippi State University Office of Research and Economic Development
- National Science Foundation [OIA-1539035, CHE-1659830]
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The first examples of pyrene-fused Janus-type N-heterocyclic germylenes (NHGe) are reported. Remarkably, the pyrene linker and the germanium containing rings are extremely twisted, with twist angles up to 64 degrees. Coordination of a Lewis base modifies the twisting of pyrene to an overall bent core (141 degrees bend angle).
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