Journal
JOURNAL OF MATERIALS CHEMISTRY A
Volume 7, Issue 46, Pages 26358-26363Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9ta10382a
Keywords
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Funding
- National Natural Science Foundation of China [21707016, 21590813]
- China Postdoctoral Science Foundation [2016M600205]
- Fundamental Research Funds for the Central Universities of China [DUT16RC(3)073]
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Energy-efficient ammonia synthesis from facile electrochemical N-2 fixation is desirable in many fields such as fertilizer production and carbon-free energy carriers. However, it remains challenging due to the difficulty of N-2 adsorption and dissociation. Here, Co single atom embedded N-doped porous carbon (CSA/NPC) was reported for electrochemical reduction of N-2 to NH3, which exhibited high activity and efficiency at room temperature and atmospheric pressure. It can rapidly convert N-2 to NH3 with an NH3 production rate of 0.86 mu mol cm(-2) h(-1) and a faradaic efficiency of 10.5% at -0.2 V vs. (RHE). The Co single atoms, N-doping and porous structure were found to be responsible for its superior performance for ammonia synthesis, where Co single atoms and N-doping can provide active sites for N-2 adsorption and dissociation and porous carbon can expose more active sites and enhance mass transfer.
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