Journal
JOURNAL OF MATERIALS CHEMISTRY A
Volume 7, Issue 48, Pages 27632-27639Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9ta11285e
Keywords
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Funding
- National Natural Science Foundation of China [21722404, 21674093, 21734008]
- International Science and Technology Cooperation Program of China (ISTCP) [2016YFE0102900]
- Zhejiang Natural Science Fund for Distinguished Young Scholars [LR17E030001]
- Fundamental Research Funds for the Central Universities [2018XZZX002-16]
- Zhejiang Province Science and Technology Key Plan [2018C01047]
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Herein, two new electron acceptors, BTTPC and BTTPC-Br, are developed through extending the conjugation of terminal electron accepting moieties with thiophene and bromine units. Such a structural design effectively improves the hole transfer of exciton dynamics in blends, revealing that BTTPC-Br and BTTPC based blends, in the presence of a smaller energetic offset as a driving force, exhibit faster hole transfer from acceptors to the polymeric donor interface, 4 times (BTTPC-Br) and 1.5 times (BTTPC) faster than 0.44 picoseconds of unmodified Y5. As a result, organic solar cells (OSCs) based on the BTTPC-Br acceptor, outperforming those of BTTPC:PBDB-T and Y5:PBDB-T, reach a power conversion efficiency of 15.22%, which is so far one of the highest among the single junction OSCs made with PBDB-T polymer donor.
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