Journal
CHEMICAL COMMUNICATIONS
Volume 55, Issue 100, Pages 15089-15092Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cc08622f
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Funding
- National Natural Science Foundation of China [21702105]
- Natural Science Foundation of Jiangsu Province, China [BK20170981]
- Nanjing Tech University
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A dehydroxylative Csp(3)-N coupling reaction assisted by triphenylphosphine has been developed through electrochemical oxidation. The reaction proceeds via anodic oxidation of triphenylphosphine to generate its corresponding radical cation, followed by reacting with hydroxyl groups to form alkoxy triphenylphosphonium ions, which are trapped by azoles or amides to construct C-N bonds. This method provides an efficient electrochemical strategy of activating hydroxyl groups to form C-N bonds under mild conditions.
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