Journal
JOURNAL OF MAGNETIC RESONANCE
Volume 280, Issue -, Pages 10-19Publisher
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jmr.2017.04.001
Keywords
Frequency-domain EPR spectroscopy; Zero-field splitting; High-spin transition-metal ion
Funding
- German Federal Ministry of Education and Research (BMBF, network project EPR-Solar)
- Deutsche Forschungsgemeinschaft (DFG) [SPP 1601, NE 2064/1-1]
- HZB's user program
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We describe frequency-domain Fourier-transform THz-EPR as a method to assign spin-coupling parameters of high-spin (S > 1/2) systems with very large zero-field splittings. The instrumental foundations of synchrotron-based FD-FT THz-EPR are presented, alongside with a discussion of frequency-domain EPR simulation routines. The capabilities of this approach is demonstrated for selected mono- and multinuclear HS systems. Finally, we discuss remaining challenges and give an outlook on the future prospects of the technique. (C) 2017 Elsevier Inc. All rights reserved.
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