Journal
JOURNAL OF LUMINESCENCE
Volume 188, Issue -, Pages 172-179Publisher
ELSEVIER
DOI: 10.1016/j.jlumin.2017.04.028
Keywords
Photo-thero-refractive glass; Ion exchange; Silver clusters; Silver nanoparticles
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Funding
- Russian Science Foundation [14-23-00136]
- Russian Science Foundation [14-23-00136] Funding Source: Russian Science Foundation
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Photo-thermo-refractive glass is now promising material for developing various elements and devices of photonics. The effect of variations in the Sb2O3 concentration in the photo-thermo-refractive glass composition on the spectral-luminescent properties of silver clusters formed with the low-temperature ion exchange is studied for the first time. The effect of temperature and duration of subsequent heat treatment of ion-exchanged glasses is investigated in detail. Silver dusters in the glasses are shown to possess broadband luminescence in the visible and NIR. Luminescent silver clusters in Sb-doped photo-thermo-refractive glasses reveal the absolute quantum yield up to 63% (lambda(ex) = 365 sun), which can be used effectively for developing luminescent sensors, white LEDs, and down-convertors for solar cells.
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