Journal
NEW JOURNAL OF CHEMISTRY
Volume 43, Issue 47, Pages 18442-18444Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9nj04743c
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- Japan Society for the Promotion of Science (JSPS) [JP26242073]
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The concise total synthesis of an unusual alkaloid, aplaminal, has been accomplished. The synthetic feature is the Buchwald-Hartwig cross-coupling between a novel triazabicyclo[3.2.1]octane core and an aromatic bromide. The practicality of our approach provides aplaminal analogs and preliminary structure-cytotoxicity relationships of an aromatic moiety were achieved.
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