4.7 Article

Reactivity of a biomimetic W(IV) bis-dithiolene complex with CO2 leading to formate production and structural rearrangement

Journal

DALTON TRANSACTIONS
Volume 48, Issue 47, Pages 17441-17444

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c9dt03906f

Keywords

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Funding

  1. GIST Research Institute (GRI) grant - GIST
  2. Basic Science Research Program through the National Research Foundation of Korea (NRF) - Ministry of Education [2018R1C1B5047260]
  3. US National Science Foundation [1807845]
  4. Direct For Mathematical & Physical Scien
  5. Division Of Chemistry [1807845] Funding Source: National Science Foundation
  6. National Research Foundation of Korea [2018R1C1B5047260] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)

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A mononuclear W(IV) bis-dithiolene complex stabilized by an oxo ligand shows a reductive reactivity toward CO2, from which formate and a dinuclear W(V) complex are generated. An unusual structural rearrangement was observed during the reaction. Structural and spectroscopic characterization for a novel triply bridged dinuclear W(V) complex is reported.

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