Journal
JOURNAL OF INORGANIC BIOCHEMISTRY
Volume 173, Issue -, Pages 152-157Publisher
ELSEVIER SCIENCE INC
DOI: 10.1016/j.jinorgbio.2017.04.021
Keywords
Hydrogen sulfide; Protoporphyrin IX; Gasotransmitters; Metal coordination
Funding
- National Science Foundation [CHE-1454747]
- Alfred P. Sloan Foundation
- Dreyfus Foundation
- NSF [CHE-0923589, CHE-1427987]
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [1427987, 1454747] Funding Source: National Science Foundation
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Hydrogen sulfide (H2S) is the most recently discovered gasotransmitter molecule joining nitric oxide and carbon monoxide. In addition to being biologically important gases, these gasotransmitters also provide distinct modes of reactivity with biomimetic metal complexes. The majority of previous investigations on the reactivity of H2S with bioinorganic models have focused on Fe-based porphyrin systems, whereas investigations with other metals remains underinvestigated. To address this gap, we report here an examination of the reactions of H2S, HS--, and S-8 with Mg-II, Cu-II, Co-II, Zn-II, Cr-II, Sn-IV. and Mn-II/III protoporphyrins.
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