Journal
CHEMICAL COMMUNICATIONS
Volume 55, Issue 54, Pages 7824-7827Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cc03491a
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- Coordenacao de Aperfeicoamento de Pessoal de Nivel Superior - Brazil (CAPES) [001]
- CNPq [303846/2014-3, 400117/2016-9]
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Layered double hydroxides (LDHs), traditional anion exchangers, can be converted into cation exchangers by topotactic reactions using aqueous solutions of alkali metal sulfates. LDHs with the composition [Mn2Al(OH)(6)](A(n-))(1/n)center dot yH(2)O (A(n-) = Cl- or NO3-, CO32-) were reacted with aqueous solutions of Na2SO4. The anion carbonate could only be partially replaced by sulfate.
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