4.7 Article

Evidencing under-barrier phenomena in a Yb(III) SMM: a joint luminescence/neutron diffraction/SQUID study

Journal

INORGANIC CHEMISTRY FRONTIERS
Volume 6, Issue 11, Pages 3152-3157

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c9qi00726a

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Funding

  1. ANR [REDIVALAN ANR-15-CE29-0019-02, SCOSIMLIGHT ANR-13-BS07-0022-01]

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We report the synthesis, spectroscopic and magnetic characterisation and ab initio investigation of a new mononuclear ytterbium based complex, [YbTp(2)NO(3)], and discuss the physical mechanisms underlying the slow relaxation of its magnetisation in a moderate static field and at low temperature.

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