Journal
JOURNAL OF CHEMICAL SCIENCES
Volume 132, Issue 1, Pages -Publisher
INDIAN ACAD SCIENCES
DOI: 10.1007/s12039-019-1717-3
Keywords
p-sulfonatocalix[6]arene; ternary system; cooperative binding
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Funding
- University Grants Commission, New Delhi
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The ternary complexes are formed by self-assembly through cooperative hydrogen bonding between p-SCX6-FL and M2+ through water molecule which is reinforced by columbic and electrostatic interactions. The binding efficiency of Cu2+ and Zn2+ is observed at a greater extent than Co2+ and Ni2+. Furthermore, the kinetic study of p-SCX6-FL-Cu2+ and Zn2+ reveals that the process of complexation is slower than the binary system (FL+p-SCX6).
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